The $currenUser object variable contains all attributes of the user entity. The Userrole is a reference between the System.User entity and System.UserRole entity. So thare is no way that you can comapre it like this bsed on a string.
Besides its not possible, I would never do it , as hardcode string comparisons will eventually break your app
But how to solve?
Is this a expression in a microflow decision?
In that case, add a retrieve before the decision and retrieve the role Administrator of the $CurrentUser
By using the token '[%UserRole_Administrator%]', you are save. When changing the Userrole name, the expression will change accordingly. When deleting the role, this expression will throw a model error.
Next check if the role is returned. If true, then the User is a Admin, otherwise not.
This is how microflow would look like
Is it for conditional visibility or other in the front-end; then it can be done using based on role