Sure it is. You have probably already seen the Excel importer in the Appstore. It is downloaded over 21000 times, so very widely used. It will however not allow you to import data the way you describe it. Two possibilities to work around this:
Since you only have column F as datavalues, there is a third option. What you can do is make E1 'Fieldname' and F1 'Fieldvalue'. Do the import via Excelimporter, get the result stored in entity having attributes 'Fieldname' and 'Fieldvalue'. Then loop over the objects of that entity