Hi Theo!
My guess is that your project doesn't contain the correct Java library since it throws a NoSuchMethodError.
I suggest you deploy your application for Eclipse and check the Java action that's being used by the SAML module. That should give you some more information.
Indeed as Willem suggests you have a Java library problem. Most of the time when this happens, it's due to a duplicate JAR file of a different (often older) version in your project/userlib folder. See these questions for more info:
https://forum.mendix.com/link/questions/88093